Preparation of a chiral Pt-12 tetrahedral cage and its use in catalytic Michael addition reaction

Bhat, Imtiyaz Ahmad and Devaraj, Aanthonisamy and Howlader, Prodip and Chi, Ki-Whan and Mukherjee, Partha Sarathi (2018) Preparation of a chiral Pt-12 tetrahedral cage and its use in catalytic Michael addition reaction. In: CHEMICAL COMMUNICATIONS, 54 (38). pp. 4814-4817.

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Abstract

The reaction of chiral cis-(1S,2S)-dch] Pt(NO3)(2) (M) where (1S,2S)-dch = (1S,2S)-1,2-diaminocyclohexane] with a hexadentate ligand (L) in 3 : 1 stoichiometric ratio yielded a 12+4] self-assembled chiral M12L4 molecular tetrahedron (T). The cage T features an internal 3D nanocavity with large open `windows', enabling it to catalyze Michael addition reactions of a series of nitrostyrene derivatives with indole in a 9 : 1 water : methanol mixture.

Item Type:	Journal Article
Publication:	CHEMICAL COMMUNICATIONS
Publisher:	ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Additional Information:	Copy right for this article belong to ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	23 May 2018 14:55
Last Modified:	23 May 2018 14:55
URI:	http://eprints.iisc.ac.in/id/eprint/59912

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