Bettadapur, Kiran R and Kapanaiah, Raja and Lanke, Veeranjaneyulu and Prabhu, Kandikere Ramaiah (2018) Weak Directing Group Steered Formal Oxidative 2+2+2]-Cyclization for Selective Benzannulation of Indoles. In: JOURNAL OF ORGANIC CHEMISTRY, 83 (4). pp. 1810-1818.
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Official URL: http://dx.doi.org/10.1021/acs.joc.7b02719
Abstract
A double C-H activation and double insertion process to achieve the synthesis benzoe]indole frameworks has been disclosed. This type of benzannulation is directed by a trifluoromethylketone moiety, which is easy to install on the indole C3-position. Overall the reaction takes places as an oxidative cyclization of two alkynes with the C4-C5 position of indole.
| Item Type: | Journal Article |
|---|---|
| Publication: | JOURNAL OF ORGANIC CHEMISTRY |
| Publisher: | AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| Additional Information: | Copy right for the article belong toAMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 03 Apr 2018 18:27 |
| Last Modified: | 03 Apr 2018 18:27 |
| URI: | http://eprints.iisc.ac.in/id/eprint/59462 |
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