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AgOTf-catalyzed dehydrative 3+2] annulation of aziridines with 2-naphthols

Kaicharla, Trinadh and Jacob, Anu and Gonnade, Rajesh G and Biju, Akkattu T (2017) AgOTf-catalyzed dehydrative 3+2] annulation of aziridines with 2-naphthols. In: CHEMICAL COMMUNICATIONS, 53 (58). pp. 8219-8222.

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Official URL: http://doi.org/10.1039/c7cc03425c


The reaction of 2-naphthols with aziridines in the presence of AgOTf resulting in a dehydrative, formal 3+2] annulation is reported. The reaction allows the synthesis of functionalized benzoindolines, and tolerates a broad range of functional groups. A preliminary study on themechanism of this reaction indicates an SN1-type ring-opening of aziridines. This method is demonstrated for the one-pot synthesis of benzoindoles.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 12 Aug 2017 04:32
Last Modified: 12 Aug 2017 04:32
URI: http://eprints.iisc.ac.in/id/eprint/57603

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