Pd-Boron-Catalyzed One Carbon Isomerization of Olefins: Water Assisted Process at Room Temperature

Ojha, Devi Prasan and Gadde, Karthik and Prabhu, Kandikere Ramaiah (2017) Pd-Boron-Catalyzed One Carbon Isomerization of Olefins: Water Assisted Process at Room Temperature. In: JOURNAL OF ORGANIC CHEMISTRY, 82 (9). pp. 4859-4865.

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Abstract

A palladium boronate/borane-system -catalyzed isomerization of olefins has been uncovered. An efficient Cy2 FG catalytic combination of Pd(OAc)(2)](3)-boronate-PCy3-enabled olefin isomerization at 80 degrees C has been investigated. Addition of water to the reaction showed a remarkable improvement and the isomerization occurred at ambient temperature. These catalytic systems function efficiently for the isomerization of functionalized as well as unfunctionalized olefms. The catalytic conditions demonstrate the involvement of both nonhydride and metal-hydride medium and can be switchable with water as an additive.

Item Type:	Journal Article
Publication:	JOURNAL OF ORGANIC CHEMISTRY
Additional Information:	Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	10 Jun 2017 04:39
Last Modified:	10 Jun 2017 04:39
URI:	http://eprints.iisc.ac.in/id/eprint/57163

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