Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative

Pete, Umesh D and Dikundwar, Amol G and Sharma, Vaishali M and Gejji, Shridhar P and Bendre, Ratnamala S and Row, Tayur N Guru (2015) Partial rotation of the isopropyl group in the solid state: single-crystal-to-single-crystal phase transformation in a carvacrol derivative. In: CRYSTENGCOMM, 17 (39). pp. 7482-7485.

PDF Cry_17-39_7482_2015.pdf - Published Version Restricted to Registered users only Download (1MB) | Request a copy

Abstract

A hitherto unseen rotation of the isopropyl group in the solid state, predicted to be forbidden based on theoretical investigations, is reported. This C-C rotation observed during the temperature dependent single-crystal-to-single-crystal transformation is attributed to the concomitant changes in molecular structure and intermolecular packing.

Item Type:	Journal Article
Publication:	CRYSTENGCOMM
Publisher:	ROYAL SOC CHEMISTRY
Additional Information:	Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	05 Nov 2015 09:00
Last Modified:	05 Nov 2015 09:00
URI:	http://eprints.iisc.ac.in/id/eprint/52701

Actions (login required)

View Item