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Investigation of the inhibition effect of ibuprofen triazole against mild steel corrosion in an acidic environment

Pavithra, MK and Venkatesha, TV and Kumar, Punith MK and Manjunatha, K (2015) Investigation of the inhibition effect of ibuprofen triazole against mild steel corrosion in an acidic environment. In: RESEARCH ON CHEMICAL INTERMEDIATES, 41 (10). pp. 7163-7177.

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Official URL: http://dx.doi.org/10.1007/s11164-014-1804-5

Abstract

The inhibition performance of ibuprofen triazole (IT) on mild steel (MS) corrosion in 1.0 M HCl and 0.5 M H2SO4 has been investigated by using electrochemical (potentiodynamic polarization and electrochemical impedance spectroscopy), gravimetric, and quantum chemical studies. Electrochemical investigation indicates that IT hampers MS corrosion via adsorption through a mixed inhibition mechanism. The protection ability of IT increases with an increasing concentration of inhibitor and decreases with increasing temperature. The adsorption of IT molecules on MS surface follows the Langmuir adsorption isotherm. Certain quantum chemical parameters were calculated to ascertain the correlation between inhibitive effect and molecular structure of IT.

Item Type: Journal Article
Publication: RESEARCH ON CHEMICAL INTERMEDIATES
Publisher: SPRINGER
Additional Information: Copy right for this article belongs to the SPRINGER, VAN GODEWIJCKSTRAAT 30, 3311 GZ DORDRECHT, NETHERLANDS
Keywords: Mild steel; Inhibitor; Acid corrosion; Adsorption; Potentiodynamic polarization; Electrochemical impedance spectroscopy
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 15 Oct 2015 06:09
Last Modified: 15 Oct 2015 06:09
URI: http://eprints.iisc.ac.in/id/eprint/52548

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