Ruthenium carbonyl clusters derived from pyrazolyl substituted diphosphazanes: Crystal and molecular structure of a triruthenium cluster featuring a triply bridging $\mu_{3}-\eta^{1}:\eta^{1}:\eta^{1}$ coordination mode of pyrazolate moiety\star

Venkatakrishnan, Thengarai S and Nethaji, Munirathinam and Krishnamurthy, Setharampattu S (2006) Ruthenium carbonyl clusters derived from pyrazolyl substituted diphosphazanes: Crystal and molecular structure of a triruthenium cluster featuring a triply bridging $\mu_{3}-\eta^{1}:\eta^{1}:\eta^{1}$ coordination mode of pyrazolate moiety\star. In: Journal of Organometallic Chemistry, 691 (1&2). pp. 224-228.

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Abstract

The radical initiated reactions of $Ru_{3}(CO)_{12}$ with pyrazolyl substituted diphosphazanes $Ph_{2}PN(R)PPh(N_{2}C_{3}HMe_{2}-3,5)$ $[R = (S)-^*CHMePh(1) or CHMe_{2}(2)]$ proceed via P-N(pyrazole) bond rupture resulting in the formation of phosphido clusters, $[Ru_{3}(CO)_{5}(\mu_{sb}-CO)_{2}(\mu_{3}-N,N'-\eta^{1}:\eta^{1}:\eta^{1}-N_{2}C_{3}HMe_{2}-3,5)$ ${\mu-P,P'-Ph_{2}PN(R)PPh}] [R=(S)-^*CHMePh(3) or CHMe_{2}(4)]$. The pyrazolate moiety adopts an unusual triply bridging $\mu_{3}-\eta^{1}:\eta^{1}:\eta^{1}$-mode of coordination in these clusters.

Item Type:	Journal Article
Publication:	Journal of Organometallic Chemistry
Publisher:	Elsevier Science BV
Additional Information:	Copyright for this article belongs to Elsevier.
Keywords:	Ruthenium carbonyl clusters;P-N ligands;Phosphane-phosphido clusters, Chirality;mu3-eta1:eta1:eta1-Pyrazolyl coordination
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	03 Feb 2006
Last Modified:	19 Sep 2010 04:23
URI:	http://eprints.iisc.ac.in/id/eprint/5212

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