4,8,9,10-Tetraphenyl-1,3-diazaadamantan-6-one acetone hemisolvate

Nandhini, Subha M and Krishnakumar, RV and Narasimhamurthy, T and Vijayakumar, V and Sundarvadivelu, M and Natarajan, S (2002) 4,8,9,10-Tetraphenyl-1,3-diazaadamantan-6-one acetone hemisolvate. In: Acta Crystallographica Section E: Structure Reports Online, 58 (11). o1210-o1212.

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Abstract

In the title compound, $C_{32}H_{28}N_{2}O·0.5C_3H_6O$, the two axial and two equatorial phenyl substituents are essentially planar. There are no hydrogen-bonded interactions between the two independent molecules in the asymmetric unit. The crystal packing is characterized by $C-H{...}O$ interactions. The solvent (acetone) molecule in the crystal structure significantly influences the packing, features of which are distinctly different from those of unsolvated 4,8,9,10-tetraphenyl-1,3-diazaadamantan-6-one and its methoxy- and chloro-substituted analogues.

Item Type:	Journal Article
Publication:	Acta Crystallographica Section E: Structure Reports Online
Publisher:	Blackwell
Additional Information:	Copyright for this article belongs to Blackwell Publishing.
Department/Centre:	Division of Physical & Mathematical Sciences > Physics
Date Deposited:	01 Feb 2007
Last Modified:	19 Sep 2010 04:23
URI:	http://eprints.iisc.ac.in/id/eprint/5175

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