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Kinetics of CO oxidation on palladium using microkinetics coupled with reaction route analysis

Mandapaka, Ravi Kiran and Madras, Giridhar (2015) Kinetics of CO oxidation on palladium using microkinetics coupled with reaction route analysis. In: CHEMICAL ENGINEERING SCIENCE, 131 . pp. 271-281.

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Official URL: http://dx.doi.org/ 10.1016/j.ces.2015.03.056


A plausible microkinetic model has been proposed for the CO oxidation reaction catalysed by palladium (Pd) with the kinetic parameters obtained from the literature. A robust rate expression using the reaction route analysis has been developed for the presented microkinetic scheme and the obtained rate expressions have been validated against the experimental data presented in the literature. A wide range of experimental conditions ranging from single Pd crystals under ultra-high vacuum conditions and impregnated Pd used for fixed bed experiments under atmospheric pressure has been used to validate the reaction mechanism. (C) 2015 Elsevier Ltd. All rights reserved.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Keywords: Microkinetic model; Reaction route analysis; Ultra-high vacuum; CO oxidation
Department/Centre: Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 15 Jun 2015 10:43
Last Modified: 15 Jun 2015 10:43
URI: http://eprints.iisc.ac.in/id/eprint/51684

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