Bhattacharjee, Subham and Bhattacharya, Santanu (2015) Role of synergistic pi-pi stacking and X-H center dot center dot center dot Cl (X = C, N, O) H-bonding interactions in gelation and gel phase crystallization. In: CHEMICAL COMMUNICATIONS, 51 (32). pp. 7019-7022.
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Official URL: http://dx.doi.org/10.1039/c5cc00930h
Abstract
The self-assembly of p-pyridyl-ended oligo-p-phenylenevinylenes (OPVs) in ethanol leads to the formation of either hollow or solid microrods. The corresponding protonated OPVs with n-butyl chains induce transparent gelation and also gel phase crystallization owing to various synergistic noncovalent interactions. The chloride ion-selective gelation, AIEE and stimuli responsiveness of the gel are also observed.
Item Type: | Journal Article |
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Publication: | CHEMICAL COMMUNICATIONS |
Publisher: | ROYAL SOC CHEMISTRY |
Additional Information: | Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND |
Keywords: | AGGREGATION-INDUCED EMISSION; METAL-ORGANIC PARTICLES; SUPRAMOLECULAR GEL; ENERGY-TRANSFER; HYDROGEL FORMATION; WATER; MODULATION; OLIGO(P-PHENYLENEVINYLENE)S; NANOSTRUCTURES; ORGANIZATION |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 13 May 2015 07:28 |
Last Modified: | 13 May 2015 07:28 |
URI: | http://eprints.iisc.ac.in/id/eprint/51534 |
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