An alluaudite Na-2+Fe-2x(2-x)(SO4)(3)(x=0.2) derivative phase as insertion host for lithium battery

Ming, Jun and Barpanda, Prabeer and Nishimura, Shin-ichi and Okubo, Masashi and Yamada, Atsuo (2015) An alluaudite Na-2+Fe-2x(2-x)(SO4)(3)(x=0.2) derivative phase as insertion host for lithium battery. In: ELECTROCHEMISTRY COMMUNICATIONS, 51 . pp. 19-22.

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Abstract

A new desodiated derivative compound, Na0.89Fe1.8(SO4)(3), was prepared by the chemical oxidation of alluaudite Na2.4Fe1.8(SO4)(3) Phase using NOBF4 as oxidant. The structure and valency of Fe were characterized by X-ray diffraction (XRD) and Fe-57 Mossbauer spectroscopy. Intercalation behavior of lithium ions in the structure of Na0.89Fe1.8(SO4)(3) was gauged by electrochemical analyses and ex-situ X-ray diffraction. A high capacity of 110 mAh g(-1) at 0.1 C was obtained with a good rate kinetics within a range of 0.1-10 C(1 C = 118 mAh g-1) involving a high Fe3+/Fe2+ redox potential of 3.75 V (vs. Li/Li+). These results confirmed that the Na2.4-delta Fe1.8(SO4)(3) framework was stable even after oxidation and forms a new competitive cathode for the reversible intercalation of lithium ions. (C) 2014 Elsevier B.V. All rights reserved.

Item Type:	Journal Article
Publication:	ELECTROCHEMISTRY COMMUNICATIONS
Publisher:	ELSEVIER SCIENCE INC
Additional Information:	Copy right for this article belongs to the ELSEVIER SCIENCE INC, 360 PARK AVE SOUTH, NEW YORK, NY 10010-1710 USA
Keywords:	Lithium batteries; Sodium batteries; Cathode; Alluaudite; Oxidation
Department/Centre:	Division of Chemical Sciences > Materials Research Centre
Date Deposited:	01 Apr 2015 12:10
Last Modified:	01 Apr 2015 12:10
URI:	http://eprints.iisc.ac.in/id/eprint/51138

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