Single-ion magnet behaviour of heptacoordinated Fe(II) complexes: on the importance of supramolecular organization

Bar, Arun Kumar and Pichon, Celine and Gogoi, Nayanmoni and Duhayon, Carine and Ramasesha, S and Sutter, Jean-Pascal (2015) Single-ion magnet behaviour of heptacoordinated Fe(II) complexes: on the importance of supramolecular organization. In: CHEMICAL COMMUNICATIONS, 51 (17). pp. 3616-3619.

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Abstract

Supramolecular organization of a metal complex may significantly contribute to the magnetization dynamics of mononuclear SMMs. This is illustrated for a heptacoordinated Fe(II) complex with rather moderate Ising-type anisotropy for which a slow magnetization relaxation with significant energy barrier was reached when this complex was properly organized in the crystal lattice. Incidentally, it is the first example of single-ion magnet behaviour of Fe(II) in a pentagonal bipyramid surrounding.

Item Type:	Journal Article
Publication:	CHEMICAL COMMUNICATIONS
Publisher:	ROYAL SOC CHEMISTRY
Additional Information:	Copy right for this article belongs to the ROYAL SOC CHEMISTRY, THOMAS GRAHAM HOUSE, SCIENCE PARK, MILTON RD, CAMBRIDGE CB4 0WF, CAMBS, ENGLAND
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	19 Mar 2015 12:09
Last Modified:	19 Mar 2015 12:09
URI:	http://eprints.iisc.ac.in/id/eprint/51054

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