Regioselective Synthesis of Vinyl Halides, Vinyl Sulfones, and Alkynes: A Tandem Intermolecular Nucleophilic and Electrophilic Vinylation of Tosylhydrazones

Ojha, Devi Prasan and Prabhu, Kandikere Ramaiah (2015) Regioselective Synthesis of Vinyl Halides, Vinyl Sulfones, and Alkynes: A Tandem Intermolecular Nucleophilic and Electrophilic Vinylation of Tosylhydrazones. In: ORGANIC LETTERS, 17 (1). pp. 18-21.

PDF org_let_17-1_18_2015.pdf - Published Version Restricted to Registered users only Download (672kB) | Request a copy

Abstract

A diazo species is trapped in an intermolecular fashion by two independent ion species in tandem at the carbene center to install an electrophile and a nucleophile on the same carbon. This metal-free concept, which is unprecedented, has been illustrated by regioselective synthesis of a variety of vinyl halides, vinyl sulfones, and alkyne derivatives.

Item Type:	Journal Article
Publication:	ORGANIC LETTERS
Publisher:	AMER CHEMICAL SOC
Additional Information:	Copyright for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	14 Feb 2015 13:33
Last Modified:	14 Feb 2015 13:33
URI:	http://eprints.iisc.ac.in/id/eprint/50805

Actions (login required)

View Item