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Solubilities of n-Butyl Esters in Supercritical Carbon Dioxide

Narayan, Ram C and Madras, Giridhar (2014) Solubilities of n-Butyl Esters in Supercritical Carbon Dioxide. In: JOURNAL OF CHEMICAL AND ENGINEERING DATA, 59 (11). pp. 3329-3334.

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Official URL: http://dx.doi.org/ 10.1021/je500309x

Abstract

The solubilities of butyl stearate and butyl laurate were determined in the temperature range of 308 K to 323 K and 313 K to 328 K, respectively, at pressures of 10 MPa to 16 MPa. The solubility of butyl laurate was higher than that of butyl stearate by almost an order in magnitude. Retrograde behavior was observed throughout the investigated pressure range. Semiempirical models such as Mendez-Teja, Chrastil, and other density-based models were used to correlate the experimental data of our work as well as several other liquid solutes.

Item Type: Journal Article
Publication: JOURNAL OF CHEMICAL AND ENGINEERING DATA
Publisher: AMER CHEMICAL SOC
Additional Information: Copyright for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Mechanical Sciences > Chemical Engineering
Date Deposited: 29 Dec 2014 05:04
Last Modified: 29 Dec 2014 05:04
URI: http://eprints.iisc.ac.in/id/eprint/50533

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