Stabilization of Co-3 - Oxoclusters in a pcu Net: Synthesis, Structure, Solvent Exchange (Single Crystal to Single Crystal) and Magnetic Studies

Bhattacharya, Saurav and Natarajan, Srinivasan (2014) Stabilization of Co-3 - Oxoclusters in a pcu Net: Synthesis, Structure, Solvent Exchange (Single Crystal to Single Crystal) and Magnetic Studies. In: ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE, 640 (14, SI). pp. 2922-2930.

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Abstract

The solvothermal reaction of CoCl(2)4H(2)O and 4,4-sulfonyldibenzoic acid (H(2)SDBA) resulted in the formation of a three-dimensional coordination polymer Co-3(C14H8O6S)(3)(DMA)(2)(MeOH)].DMA (Ia) consisting of trinuclear Co-3 oxo-cluster units. The Co-3 trimeric units are connected by SDBA(2-) anions leading to a three dimensional structure with a pcu topology. The terminal methanol molecules could be exchanged in a single crystal to single crystal (SCSC) fashion by other similar solvent molecules (ethanol, acetonitrile, water, ethyleneglycol). Magnetic studies on the parent compound, Ia, indicate antiferromagnetic interactions between the central metal atoms.

Item Type:	Journal Article
Publication:	ZEITSCHRIFT FUR ANORGANISCHE UND ALLGEMEINE CHEMIE
Publisher:	WILEY-V C H VERLAG GMBH
Additional Information:	Copyright for this article belongs to the WILEY-V C H VERLAG GMBH, BOSCHSTRASSE 12, D-69469 WEINHEIM, GERMANY
Keywords:	Coordination polymer; Cobalt; Solvent exchange; Single crystal to single crystal; Cluster compounds; Solvothermal
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	20 Dec 2014 04:40
Last Modified:	20 Dec 2014 04:40
URI:	http://eprints.iisc.ac.in/id/eprint/50479

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