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Dynamical facilitation governs glassy dynamics in suspensions of colloidal ellipsoids

Mishra, Chandan K and Nagamanasa, Hima K and Ganapathy, Rajesh and Sood, AK and Gokhale, Shreyas (2014) Dynamical facilitation governs glassy dynamics in suspensions of colloidal ellipsoids. In: PROCEEDINGS OF THE NATIONAL ACADEMY OF SCIENCES OF THE UNITED STATES OF AMERICA, 111 (43). pp. 15362-15367.

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Official URL: http://dx.doi.org/ 10.1073/pnas.1413384111


One of the greatest challenges in contemporary condensed matter physics is to ascertain whether the formation of glasses from liquids is fundamentally thermodynamic or dynamic in origin. Although the thermodynamic paradigm has dominated theoretical research for decades, the purely kinetic perspective of the dynamical facilitation (DF) theory has attained prominence in recent times. In particular, recent experiments and simulations have highlighted the importance of facilitation using simple model systems composed of spherical particles. However, an overwhelming majority of liquids possess anisotropy in particle shape and interactions, and it is therefore imperative to examine facilitation in complex glass formers. Here, we apply the DF theory to systems with orientational degrees of freedom as well as anisotropic attractive interactions. By analyzing data from experiments on colloidal ellipsoids, we show that facilitation plays a pivotal role in translational as well as orientational relaxation. Furthermore, we demonstrate that the introduction of attractive interactions leads to spatial decoupling of translational and rotational facilitation, which subsequently results in the decoupling of dynamical heterogeneities. Most strikingly, the DF theory can predict the existence of reentrant glass transitions based on the statistics of localized dynamical events, called excitations, whose duration is substantially smaller than the structural relaxation time. Our findings pave the way for systematically testing the DF approach in complex glass formers and also establish the significance of facilitation in governing structural relaxation in supercooled liquids.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the NATL ACAD SCIENCES, 2101 CONSTITUTION AVE NW, WASHINGTON, DC 20418 USA
Keywords: glass transition; dynamical facilitation; anisotropic colloids
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 04 Dec 2014 04:47
Last Modified: 04 Dec 2014 04:47
URI: http://eprints.iisc.ac.in/id/eprint/50362

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