Bali, Amit K and Sunnam, Sunil K and Prasad, Kavirayani R (2014) Enantiospecific Total Synthesis of Macrolactone Sch 725674. In: ORGANIC LETTERS, 16 (15). pp. 4001-4003.
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Official URL: http://dx.doi.org/ 10.1021/ol5018678
Abstract
The enantiospecific total synthesis of 14-membered macrolactone Sch 725674 was accomplished from tartaric acid. Key reactions in the synthesis include the Ley's dithiaketalization of an alkynone derived from the bis-Weinreb amide of tartaric acid, Boord olefination, and ring-closing metathesis of an acrylate ester.
| Item Type: | Journal Article |
|---|---|
| Publication: | ORGANIC LETTERS |
| Publisher: | AMER CHEMICAL SOC |
| Additional Information: | Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 04 Sep 2014 11:04 |
| Last Modified: | 04 Sep 2014 11:04 |
| URI: | http://eprints.iisc.ac.in/id/eprint/49766 |
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