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Enantiospecific Total Synthesis of Macrolactone Sch 725674

Bali, Amit K and Sunnam, Sunil K and Prasad, Kavirayani R (2014) Enantiospecific Total Synthesis of Macrolactone Sch 725674. In: ORGANIC LETTERS, 16 (15). pp. 4001-4003.

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Official URL: http://dx.doi.org/ 10.1021/ol5018678


The enantiospecific total synthesis of 14-membered macrolactone Sch 725674 was accomplished from tartaric acid. Key reactions in the synthesis include the Ley's dithiaketalization of an alkynone derived from the bis-Weinreb amide of tartaric acid, Boord olefination, and ring-closing metathesis of an acrylate ester.

Item Type: Journal Article
Additional Information: Copy right for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 04 Sep 2014 11:04
Last Modified: 04 Sep 2014 11:04
URI: http://eprints.iisc.ac.in/id/eprint/49766

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