ePrints@IIScePrints@IISc Home | About | Browse | Latest Additions | Advanced Search | Contact | Help

Catalytic Enantioselective Iodoaminocyclization of Hydrazones

Tripathi, Chandra Bhushan and Mukherjee, Santanu (2014) Catalytic Enantioselective Iodoaminocyclization of Hydrazones. In: ORGANIC LETTERS, 16 (12). pp. 3368-3371.

[img] PDF
Org-Let_16-12-3368-3371-2014.pdf.pdf - Published Version
Restricted to Registered users only

Download (576kB) | Request a copy
Official URL: http://dx.doi.org/10.1021/ol5013982

Abstract

The first catalytic enantioselective iodoaminocyclization of beta,gamma-unsaturated hydrazones has been developed with the help of a trans-1,2-diaminocyclohexane-derived bifunctional thiourea catalyst and allows for the direct access to Delta(2)-pyrazolines containing a quaternary stereogenic center in high yield with good enantioselectivity (up to 95% yield and 95:5 er).

Item Type: Journal Article
Publication: ORGANIC LETTERS
Publisher: AMER CHEMICAL SOC
Additional Information: copyright for this article belongs to AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 14 Aug 2014 09:53
Last Modified: 14 Aug 2014 09:53
URI: http://eprints.iisc.ac.in/id/eprint/49547

Actions (login required)

View Item View Item