Total synthesis of (+)-anamarine

Prasad, Kavirayani R and Kumar, Mothish S (2014) Total synthesis of (+)-anamarine. In: TETRAHEDRON, 70 (30). pp. 4552-4556.

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Abstract

An enantiospecific total synthesis of polyhydroxy delta-pyrone natural product (+)-anamarine is accomplished. The main features of the synthesis include the stereoselective reduction of the ketone obtained by the desymmetrization of the bis-dimethyl amide of tartaric acid and further elaboration involving asymmetric Brown's allylation and ring closing metathesis. (C) 2014 Elsevier Ltd. All rights reserved.

Item Type:	Journal Article
Publication:	TETRAHEDRON
Publisher:	PERGAMON-ELSEVIER SCIENCE LTD
Additional Information:	Copyright for this article belongs to the PERGAMON-ELSEVIER SCIENCE LTD, THE BOULEVARD, LANGFORD LANE, KIDLINGTON, OXFORD OX5 1GB, ENGLAND
Keywords:	Anamarine; Polyhydroxy lactone; delta-Pyrone
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	11 Aug 2014 04:33
Last Modified:	11 Aug 2014 04:33
URI:	http://eprints.iisc.ac.in/id/eprint/49529

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