Roy, Subhendu and Jemmis, Eluyathingal D (2014) Unexpected mechanism for formal 2+2] cycloadditions of metallacyclocumulenes. In: CURRENT SCIENCE, 106 (9). pp. 1249-1254.
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Abstract
The formation of radialene complex 6M proceeds through a three-membered metallacyclopropene complex 7M, contrary to the prevailing notion of simple dimerization of metallacyclocumulene 1M. The 1M-7M equilibrium, which is predominantly governed by the size-dependent ligand binding of the metal atoms, plays a decisive role in the chemistry of Cp2M-ligand complexes. This size dependency is further fine-tuned by the substituents on the substrates and helps in exploiting these classes of metallacycles to generate new chemistry.
| Item Type: | Journal Article |
|---|---|
| Publication: | CURRENT SCIENCE |
| Publisher: | INDIAN ACAD SCIENCES |
| Additional Information: | copyright for this article belongs to INDIAN ACAD SCIENCES, C V RAMAN AVENUE, SADASHIVANAGAR, P B #8005, BANGALORE 560 080, INDIA |
| Keywords: | Cumulene; metallacycles; radialene complex; transition metals |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 24 Jun 2014 06:37 |
| Last Modified: | 24 Jun 2014 06:37 |
| URI: | http://eprints.iisc.ac.in/id/eprint/49310 |
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