Kaur, Ramanpreet and Lalithalakshmi, Bannur V and Row, Tayur Guru N (2014) Symbiosis in Solid State Interconversion and Synthon Modularity in Hydroxybenzoic Acid-Hexamine Adducts. In: CRYSTAL GROWTH & DESIGN, 14 (5). pp. 2614-2620.
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Systematic cocrystallization of hydroxybenzoic acids with hexamine using liquid-assisted grinding shows facile solid state interconversion among different stoichiometric variants. The reversible interconversion caused by varying both the acid and base components in tandem is shown to be a consequence of hydrogen-bonded synthon modularity present in all representative crystal structures. Among a total of 11 complexes, three are salts and eight are cocrystals. The insulated synthons appear as conserved tetrameric motifs in the structures, and the mechanism of interconversion is closely monitored by the synthon modularity. The interconversion is consistent with the theoretically computed stabilization energies of all the tetramers found in this series of cocrystals based on atoms in molecule calculations.
| Item Type: | Journal Article |
|---|---|
| Publication: | CRYSTAL GROWTH & DESIGN |
| Publisher: | AMER CHEMICAL SOC |
| Additional Information: | Copyright for this article belongs to the AMER CHEMICAL SOC, 1155 16TH ST, NW, WASHINGTON, DC 20036 USA |
| Department/Centre: | Division of Chemical Sciences > Solid State & Structural Chemistry Unit |
| Date Deposited: | 17 Jun 2014 11:00 |
| Last Modified: | 17 Jun 2014 11:01 |
| URI: | http://eprints.iisc.ac.in/id/eprint/49254 |
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