A Dinuclear Cadmium(II) Schiff Base Thiocyanato Complex: Crystal Structure and Fluorescence

Shit, Shyamapada and Sankolli, Ravish and Row, Guru Tayur N (2014) A Dinuclear Cadmium(II) Schiff Base Thiocyanato Complex: Crystal Structure and Fluorescence. In: ACTA CHIMICA SLOVENICA, 61 (1). 59+.

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Abstract

A new dinuclear cadmium(II) complex, Cd(L)(NCS)](2) (1) has been synthesized using a potentially tetradentate Schiff base ligand HL, 2-((E)-(2-(diethylamino) ethylimino) methyl)-6-methoxyphenol, obtained by the condensation of 2-diethylaminoethylamine and o-vanillin, and characterized by different physicochemical techniques. Crystal structure of the title complex was unambiguously established by single crystal X-ray diffraction which reveals that metal centers are connected by bridging phenolato and chelating methoxy oxygen atoms of the coordinating Schiff bases and embedded in severely distorted octahedral geometries. Fluorescence properties of the ligand and its complex, studied at room temperature indicate that later may serve as strong fluorescent

Item Type:	Journal Article
Publication:	ACTA CHIMICA SLOVENICA
Publisher:	SLOVENSKO KEMIJSKO DRUSTVO
Additional Information:	copyright for this article belongs to SLOVENSKO KEMIJSKO DRUSTVO, HAJDRIHOVA 19, LJUBLJANA 1000, SLOVENIA
Keywords:	Cadmium(II); Schiff base; Characterization; Crystal structure; Fluorescence
Department/Centre:	Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited:	03 Jun 2014 08:33
Last Modified:	03 Jun 2014 08:33
URI:	http://eprints.iisc.ac.in/id/eprint/49106

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