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Reduced graphene oxide induced phase miscibility in polystyrene-poly(vinyl methyl ether) blends

Xavier, Priti and Sharma, Keshav and Elayaraja, K and Vasu, KS and Sood, AK and Bose, Suryasarathi (2014) Reduced graphene oxide induced phase miscibility in polystyrene-poly(vinyl methyl ether) blends. In: RSC ADVANCES, 4 (24). pp. 12376-12387.

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Official URL: http://dx.doi.org/10.1039/c3ra46902f


Graphene oxide and reduced graphene oxide (r-GO) were synthesized by wet chemistry and the effect of r-GO in PS-PVME blends was investigated here with respect to phase miscibility, intermolecular cooperativity in the glass transition region and concentration fluctuation variance by shear rheology and dielectric spectroscopy. The spinodal decomposition temperature (T-s) and correlation length were evaluated from isochronal temperature scans in shear rheology. The r-GO is shown to induce miscibility in the blends, which may lead to increased local heterogeneity in the blends, though the length of cooperatively re-arranged regions (xi) at T-g is more or less unaltered. The evolution of the phase morphology as a function of temperature was assessed using polarized optical microscopy (POM). In the case of the 60/40 PS-PVME blends with 0.25 wt% r-GO, apart from significant refinement in the morphology, retention of the interconnected ligaments of PVME was observed, even in the late stages of phase separation suggesting that the coarsening of the phase morphology has been slowed down in the presence of r-GO. This phenomenon was also supported by AFM. Surface enrichment of PVME, owing to its lower surface tension, in the demixed samples was supported by XPS scans. The interconnected network of PVME has resulted in significantly higher permittivity in the bi-phasic blends, although the concentration of r-GO is below the percolation threshold.

Item Type: Journal Article
Publication: RSC ADVANCES
Additional Information: Copyright for this article belongs to the ROYAL SOC CHEMISTRY, ENGLAND
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Division of Physical & Mathematical Sciences > Physics
Date Deposited: 12 May 2014 09:49
Last Modified: 12 May 2014 09:49
URI: http://eprints.iisc.ac.in/id/eprint/48933

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