Manna, Madhu Sudan and Mukherjee, Santanu (2014) Remarkable influence of secondary catalyst site on enantioselective desymmetrization of cyclopentenedione. In: CHEMICAL SCIENCE, 5 (4). pp. 1627-1633.
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Official URL: http://dx.doi.org/10.1039/c3sc53102c
Abstract
An efficient, robust and highly enantioselective catalytic desymmetrization of 2,2-disubstituted cyclopentene-1,3-diones is developed via direct vinylogous nucleophilic addition of deconjugated butenolides. A remarkable influence of the secondary catalyst site on the enantioselectivity points towards an intriguing mechanistic scenario, possibly by triggering a change in catalyst conformation.
Item Type: | Journal Article |
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Publication: | CHEMICAL SCIENCE |
Publisher: | ROYAL SOC CHEMISTRY |
Additional Information: | Copyright for this article belongs to the ROYAL SOC CHEMISTRY, ENGLAND |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 12 May 2014 05:36 |
Last Modified: | 12 May 2014 05:36 |
URI: | http://eprints.iisc.ac.in/id/eprint/48922 |
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