Ayya, Chinna Swamy P and Thilagar, Pakkirisamy (2014) Effect of substituent position on optical properties of boron-dipyrromethane isomers. In: INORGANICA CHIMICA ACTA, 411 . pp. 97-101.
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Official URL: http://dx.doi.org/10.1016/j.ica.2013.11.032
Abstract
Three isomeric meso-SiMe3C6H4 substituted BODIPYs have been synthesized and their optical properties studied. The constitutional isomers show similar absorption properties but vastly different emissive properties as a result of their different conformational flexibility. Fluorine-19 NMR study is used to unravel the conformational state of the BODIPY isomers at a molecular level. (C) 2013 Elsevier B. V. All rights reserved.
Item Type: | Journal Article |
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Publication: | INORGANICA CHIMICA ACTA |
Publisher: | ELSEVIER SCIENCE SA |
Additional Information: | Copyright for this article belongs to the ELSEVIER SCIENCE SA, SWITZERLAND |
Keywords: | BODIPY; Fluorescence; X-ray crystal structure; Molecular symmetry |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 10 Mar 2014 07:28 |
Last Modified: | 10 Mar 2014 07:28 |
URI: | http://eprints.iisc.ac.in/id/eprint/48544 |
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