Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation

Roy, Soumya Jyoti Singha and Mukherjee, Santanu (2014) Enantioselective desymmetrization of prochiral 1,3-dinitropropanes via organocatalytic allylic alkylation. In: CHEMICAL COMMUNICATIONS, 50 (1). pp. 121-123.

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Abstract

An enantioselective desymmetrization of prochiral 1,3-dinitropropanes has been developed which proceeds via enantiogroup differentiating organocatalytic allylic alkylation. Densely functionalized products with two vicinal stereocenters were obtained generally with good to excellent diastereoselectivity (up to >20:1 dr) and superb enantioselectivity (up to >99:1 er).

Item Type:	Journal Article
Publication:	CHEMICAL COMMUNICATIONS
Publisher:	ROYAL SOC CHEMISTRY
Additional Information:	copyright for this article belongs to ROYAL SOC CHEMISTRY, ENGLAND
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	16 Jan 2014 10:30
Last Modified:	16 Jan 2014 10:33
URI:	http://eprints.iisc.ac.in/id/eprint/48043

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