Revisiting borylanilines: unique solid-state structures and insight into photophysical properties

Sudhakar, Pagidi and Mukherjee, Sanjoy and Thilagar, Pakkirisamy (2013) Revisiting borylanilines: unique solid-state structures and insight into photophysical properties. In: Organometallics, 32 (10). pp. 3129-3133.

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Abstract

The structure and photophysical properties of two known borylanilines, 4-(dimesitylboryl)aniline (1) and 4-(dimesitylboryl)-3,5-dimethylaniline (2), have been investigated. 1 and 2 have similar donor and acceptor centers but differ in their molecular conformations. Compounds 1 and 2 have been structurally characterized, and they exhibit a rare form of intermolecular N-H - - -pi electrostatic interactions. The structure and photophysical properties of 1 and 2 are discussed in the context of computational results.

Item Type:	Journal Article
Publication:	Organometallics
Publisher:	American Chemical Society
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	18 Jul 2013 07:04
Last Modified:	18 Jul 2013 07:04
URI:	http://eprints.iisc.ac.in/id/eprint/46865

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