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Elastic properties of fast ion conducting lithium based borate glasses

Gowda, Veeranna VC and Anavekar, RV and Rao, KJ (2004) Elastic properties of fast ion conducting lithium based borate glasses. In: Journal of Non-Crystalline Solids, 351 (43-45). pp. 3421-3429.

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Elastic properties of $Li_{2}O-PbO-B_{2}O_{3}$ glasses have been investigated using sound velocity measurements at 10 MHz. Four series of glasses have been investigated with different concentrations of $Li_{2}O$, PbO and $B_{2}O_{3}$. The variations of molar volume have been examined for the influences of $Li_{2}O$ and PbO. The elastic moduli reveal trends in their compositional dependence. The bulk and shear modulus increases monotonically with increase in the concentration of tetrahedral boron which increases network dimensionality. The variation of bulk moduli has also been correlated to the variation in energy densities. The Poisson's ratio found to be insensitive to the concentration of tetrahedral boron in the structure. The experimental Debye temperatures are in good agreement with the expected theoretical values. Experimental observations have been examined in view, the presence of borate network and the possibility of non-negligible participation of lead in network formation.

Item Type: Journal Article
Publication: Journal of Non-Crystalline Solids
Publisher: Elsevier Science BV
Additional Information: Copyright for this article belongs to Elsevier.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Division of Physical & Mathematical Sciences > Physics
Date Deposited: 15 Dec 2005
Last Modified: 19 Sep 2010 04:22
URI: http://eprints.iisc.ac.in/id/eprint/4670

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