Synthesis, Spectral Characterization, Crystal Structure and Thermal Behavior of Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate

Kalaivani, D and Malarvizhi, R and Nethaji, M (2012) Synthesis, Spectral Characterization, Crystal Structure and Thermal Behavior of Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate. In: JOURNAL OF CHEMICAL CRYSTALLOGRAPHY, 42 (11). pp. 1098-1104.

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Abstract

Tert-butyl 2,2-bis(2,4-dinitrophenyl)ethanoate was prepared from the ethanolic solution of 1-chloro-2,4-dinitrobenzene, tert-butyl 3-oxobutanoate and triethylamine. Acetyl group in tert-butyl 3-oxobutanoate has cleaved off during the formation of the title molecule. UV-VIS, IR, 1H NMR, 13C NMR, Proton-Proton COSY data and single crystal XRD results support the proposed structure. Flammability test, impact sensitivity test and TG/DTA studies at different heating rates on the synthesized molecule imply that it is an insensitive high energy density material.

Item Type:	Journal Article
Publication:	JOURNAL OF CHEMICAL CRYSTALLOGRAPHY
Publisher:	Springer Science+Business Media
Additional Information:	Copyright for this article belongs to Springer Science+Business Media New York
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	31 Dec 2012 05:59
Last Modified:	31 Dec 2012 05:59
URI:	http://eprints.iisc.ac.in/id/eprint/45480

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