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A Raman study of the interaction of electron-donor and -acceptor molecules with chemically doped graphene

Gopalakrishnan, K and Moses, Kota and Dubey, Prashant and Rao, CNR (2012) A Raman study of the interaction of electron-donor and -acceptor molecules with chemically doped graphene. In: JOURNAL OF MOLECULAR STRUCTURE, 1023 (SI). pp. 2-6.

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Official URL: http://dx.doi.org/10.1016/j.molstruc.2011.12.031


Effect of interaction of tetracyanoethylene (TCNE) and tetrathia fulvalene (TTF) with boron- and nitrogen-doped graphene has been investigated by Raman spectroscopy. The G- and 2D bands of boron- and nitrogen-doped graphenes in the Raman spectra show significantly different changes on interaction with electron-donor and -acceptor molecules. Thus, tetracyanoethylene (TCNE) and tetrathiafulvalene (TTF) have different effects on the Raman spectra of boron- and nitrogen-doped graphenes. The changes in the Raman spectra brought about by electron-donor and -acceptor molecules can be understood in general terms on the basis of molecular charge transfer. (c) 2012 Elsevier B.V. All rights reserved.

Item Type: Journal Article
Additional Information: Copyright for this article belongs to Elsevier
Keywords: Doped graphenes; Doped SWNTs; Molecular charge-transfer; Raman spectroscopy
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 11 Jan 2013 09:13
Last Modified: 11 Jan 2013 09:13
URI: http://eprints.iisc.ac.in/id/eprint/45274

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