Prasad, Kavirayani R and Gutala, Phaneendra (2012) Total synthesis of (+)-phomopsolide B. In: TETRAHEDRON, 68 (36). pp. 7489-7493.
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Official URL: http://dx.doi.org/10.1016/j.tet.2012.06.002
Abstract
An enantiospecific total synthesis of polyhydroxy delta-pyrone natural product phomopsolide B is accomplished. The main feature of the synthesis is the installation of the required E-olefin by Horner-Emmons-Wordsworth reaction and the formation of the lactone involving Still-Gennari olefination followed by lactonization. (C) 2012 Elsevier Ltd. All rights reserved.
| Item Type: | Journal Article |
|---|---|
| Publication: | TETRAHEDRON |
| Publisher: | PERGAMON-ELSEVIER SCIENCE LTD |
| Additional Information: | Copyright for this article belongs to Elseier Science |
| Keywords: | Phomopsolide B; Polyhydroxy lactone; delta-Pyrone |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 17 Dec 2012 07:41 |
| Last Modified: | 17 Dec 2012 07:41 |
| URI: | http://eprints.iisc.ac.in/id/eprint/45161 |
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