Krishnamurthya, SS and Ramachandrana, K and Woods, Michael (1981) Studies of phosphazenes .11. syntheses and structures of bis(primary amino)hexachlorocyclotetraphosphazenes and their dimethylamino derivatives. In: Phosphorus, Sulfur, and Silicon and the Related Elements, 9 (3). pp. 323-328.
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The bis(amino)hexachlorocyclotetraphosphazenes, 2-trans-6-N4P4 (NHR)2Cl6, R [dbnd] Me, Pr n Pr i , Bu n , CH2Ph, Ph, are obtained from the reaction of N4P4Cl8 with four mol. equivalents of the appropriate amine. Isomers with 2,4-structures have been isolated for R [dbnd] Bu n , CH2Ph. The 1H and 31P NMR spectra of these bis(amino) compounds and of their dimethylamino derivatives, 2-trans-6-N4P4 (NMe2)6 (NHR)2 are discussed.
| Item Type: | Journal Article |
|---|---|
| Publication: | Phosphorus, Sulfur, and Silicon and the Related Elements |
| Publisher: | Taylor and Francis Group |
| Additional Information: | Copyright of this article belongs to Taylor and Francis Group. |
| Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
| Date Deposited: | 16 Feb 2012 06:42 |
| Last Modified: | 16 Feb 2012 06:42 |
| URI: | http://eprints.iisc.ac.in/id/eprint/43291 |
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