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Thermal properties of 3BaO–3TiO2–B2O3 glasses

Varma, KBR and Vaish, Rahul (2009) Thermal properties of 3BaO–3TiO2–B2O3 glasses. In: Philosophical Magazine, 89 (19). pp. 1555-1564.

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Official URL: http://www.tandfonline.com/doi/abs/10.1080/1478643...


Transparent glasses in the system 3BaO–3TiO2–B2O3 (BTBO) were fabricated via the conventional melt-quenching technique. The as-quenched samples were confirmed to be non-crystalline by differential thermal analysis (DTA). Thermal parameters were evaluated using non-isothermal DTA experiments. The Kauzmann temperature was found to be 759 K based on heating-rate-dependent glass transition and crystallization temperatures. A theoretical relation for the temperature-dependent viscosity is proposed for these glasses and glass-ceramics.

Item Type: Journal Article
Publication: Philosophical Magazine
Publisher: Taylor and Francis Group
Additional Information: Copyright of this article belongs to Taylor and Francis Group.
Keywords: calorimetry;crystallization;glass;glass ceramics;glass transition;kinetics
Department/Centre: Division of Chemical Sciences > Materials Research Centre
Date Deposited: 23 Feb 2012 06:07
Last Modified: 23 Feb 2012 06:07
URI: http://eprints.iisc.ac.in/id/eprint/43194

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