An Enantiospecific Formal Total Synthesis of the 5-8-5 Tricyclic Diterpene ent-Fusicoauritone

Srikrishna, A and Nagaraju, Gopalasetty (2012) An Enantiospecific Formal Total Synthesis of the 5-8-5 Tricyclic Diterpene ent-Fusicoauritone. In: Synlett (1). pp. 123-127.

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Abstract

An enantiospecific formal total synthesis of the 5-8-5 tricyclic diterpene fusicoauritone has been accomplished, starting from 5-isopropyl-2-methylcyclopent-1-enemethanol [available in three steps from (R)-dihydrolimonene] employing two ring-closing-metathesis reactions for the construction of the eight- and five-membered rings.

Item Type:	Journal Article
Publication:	Synlett
Publisher:	Thieme Medical Publishers
Additional Information:	Copyright of this article belongs to Thieme Medical Publishers.
Keywords:	fusicoccanes;limonene;enantiospecific synthesis; cyclooctanoids;ring-closing metathesis
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	27 Jan 2012 06:26
Last Modified:	27 Jan 2012 06:26
URI:	http://eprints.iisc.ac.in/id/eprint/43147

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