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Activities of oxygen and lead in Pb-Ag O solutions

Jacob, KT and Jeffes, JHE (1971) Activities of oxygen and lead in Pb-Ag O solutions. In: The Journal of Chemical Thermodynamics, 3 (4). pp. 433-443.

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Official URL: http://dx.doi.org/10.1016/S0021-9614(71)80026-5


The reversible e.m.f. of galvanic cells: stainlesssteel,Ir,Pb+PbO|CaO+ZrO2|Ag+Pb+PbO,Ir,stainlesssteel,I and Pt,Ni+NiO|CaO+ZrO2|O(Pb+Ag),Cermet,Pt,II incorporating solid oxide electrolytes were measured as a function of alloy composition. In lead-rich alloys, the temperature dependence of the e.m.f. of cell I was also investigated. Since the solubility of oxygen in the alloy is small, the relative partial molar properties of lead in the binary Ag + Pb system can be calculated from the e.m.f. of this cell. The Gibbs free energies obtained in this study are combined with selected calorimetric data to provide a complete thermodynamic discription of liquid Ag + Pb Alloys. The activity coefficient of oxygen in the whole range of Ag + Pb alloys at 1273 K have been obtained from the e.m.f. of cell II; and these are found to deviate positively from Alcock and Richardson's quasichemical equation when the average co-ordination number of all the atoms is assigned a value of 2.

Item Type: Journal Article
Publication: The Journal of Chemical Thermodynamics
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Mechanical Sciences > Materials Engineering (formerly Metallurgy)
Date Deposited: 07 Dec 2011 04:54
Last Modified: 07 Dec 2011 04:54
URI: http://eprints.iisc.ac.in/id/eprint/42453

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