An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines

Alagiri, Kaliyamoorthy and Siddappa, Guralamatta and Kumara, Ravi and Prabhu, Kandikere Ramaiah (2011) An oxidative cross-dehydrogenative-coupling reaction in water using molecular oxygen as the oxidant: vanadium catalyzed indolation of tetrahydroisoquinolines. In: Chemical Communications, 47 (42). pp. 11787-11789.

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Abstract

An aerobic oxidative cross-dehydrogenative coupling reaction between sp(3) C-H and sp(2) C-H bonds is developed by employing a vanadium catalyst (10 mol%) in an aqueous medium using molecular oxygen as the oxidant. This environmentally benign strategy exhibits larger substrate scope and shows high regioselectivity.

Item Type:	Journal Article
Publication:	Chemical Communications
Publisher:	Royal Society of Chemistry
Additional Information:	Copyright of this article belongs to Royal Society of Chemistry.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	17 Nov 2011 09:46
Last Modified:	17 Nov 2011 09:46
URI:	http://eprints.iisc.ac.in/id/eprint/42105

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