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Raman study of stoichiometric and Zn-doped Fe3O4

Gupta, Rajeev and Sood, AK and Metcalf, P and Honig, JM (2002) Raman study of stoichiometric and Zn-doped Fe3O4. In: Physical Review B, 65 (10). 104430/1-8.


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We report here our Raman studies on Fe3–xZnxO4(x = 0,0.015,0.03) across the Verwey transition in the temperature range 20–300 K. The changes in Raman spectra as a function of doping show that the changes are gradual for samples with higher Zn doping. Allen's formula has been used to estimate the strength of electron-phonon interaction from the observed lineshape parameters. These estimates show that there is strong electron-phonon coupling in this system and is highest for the T mode in comparison to A1g and T modes.

Item Type: Journal Article
Publication: Physical Review B
Publisher: American Physical Society (APS)
Additional Information: Copyright for this article belongs to American Physical Society (APS).
Department/Centre: Division of Physical & Mathematical Sciences > Physics
Date Deposited: 18 Jan 2007
Last Modified: 19 Sep 2010 04:12
URI: http://eprints.iisc.ac.in/id/eprint/421

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