Towards an enantiospecific total synthesis of garsubellin A and related phloroglucin natural products: the alpha-pinene approach

Mehta, Goverdhan and Bera, Mrinal K (2004) Towards an enantiospecific total synthesis of garsubellin A and related phloroglucin natural products: the alpha-pinene approach. In: Tetrahedron Letters, 45 (6). pp. 1113-1116.

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Abstract

The first enantiospecific approach to garsubellin A and related phloroglucin natural product nemorosone, of contemporary interest from (−)alpha -pinene, has been delineated. Through a series of stereospecific operations, the requisite stereochemistry of the prenyl groups has been secured. Kende cyclization has been employed as the key step to construct the functionalized bicyclo[3.3.1]nonane core.

Item Type:	Journal Article
Publication:	Tetrahedron Letters
Publisher:	Elsevier Science Ltd.
Additional Information:	Copyright for this article belongs to Elsevier Science Ltd.
Department/Centre:	Division of Chemical Sciences > Organic Chemistry
Date Deposited:	22 Jun 2004
Last Modified:	19 Sep 2010 04:12
URI:	http://eprints.iisc.ac.in/id/eprint/414

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