Srikrishna, A and Dethe, Dattatraya H (2011) Enantiospecific first total synthesis of cucumin-H. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 50 (8). pp. 1092-1106.
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Official URL: http://nopr.niscair.res.in/handle/123456789/12513
Abstract
Enantiospecific first total synthesis of the linear triquinane sesquiterpene cucumin-H has been described. (R)-Limonene has been employed as the chiral starting material and a combination of Claisen rearrangement, intramolecular cyclopropanation and Nazarov reactions are employed for the regio- and stereospecific construction of the triquinane framework.
Item Type: | Journal Article |
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Publication: | Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry |
Publisher: | National Institute of Science Communication and Information Resources |
Additional Information: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
Keywords: | Cucumanes;triquinanes;limonene;Nazarov cyclisation;Claisen rearrangement;intramolecular cyclopropanation |
Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
Date Deposited: | 15 Sep 2011 11:01 |
Last Modified: | 15 Sep 2011 11:01 |
URI: | http://eprints.iisc.ac.in/id/eprint/40454 |
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