Ghosh, Suhrit and Ramakrishnan, S (2004) Aromatic Donor–Acceptor Charge-Transfer and Metal-Ion-Complexation-Assisted Folding of a Synthetic Polymer**. In: Angewandte Chemie International Edition, 43 (25). pp. 3264-3268.
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Abstract
Synthetic polymers typically adopt a random-coil conformation in solution primarily driven by the tendency to maximize entropy. Generation of well-defined secondary structures in synthetic polymers, therefore, will need to include specific intrachain intersegment interactions that will provide adequate enthalpic contribution to overcome this entropic penalty associated with the formation of well ordered conformations.
Item Type: | Journal Article |
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Publication: | Angewandte Chemie International Edition |
Publisher: | Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim |
Additional Information: | The copyright belongs to Wiley-VCH Verlag GmbH & Co. KGaA, Weinheim. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 17 Nov 2005 |
Last Modified: | 19 Sep 2010 04:21 |
URI: | http://eprints.iisc.ac.in/id/eprint/4022 |
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