Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2)Ru(H)(2)] (dppm = Ph2PCH2PPh2): Synthesis and crystal structure of a methanedithiolate complex

Gandhi, Thirumanavelan and Nethaji, Munirathinam and Jagirdar, Balaji R (2003) Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2)Ru(H)(2)] (dppm = Ph2PCH2PPh2): Synthesis and crystal structure of a methanedithiolate complex. In: Inorganic Chemistry, 42 (3). 667-669 .

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Abstract

Addition of excess carbon disulfide to cis/trans-[(dPPM)(2)Ru(H)(2)] results in the methanedithiolate complex [(dppm)(2)Ru(eta(2)-S2CH2)] 4 via the intermediacy of cis-[(dppm)(2)Ru(H)(SC(S)H)] 2. The X-ray crystal structure of this species has been determined.

Item Type:	Journal Article
Publication:	Inorganic Chemistry
Publisher:	American Chemical Society
Additional Information:	Copyright of this article belongs to American Chemical Society.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	25 Aug 2011 09:41
Last Modified:	25 Aug 2011 09:41
URI:	http://eprints.iisc.ac.in/id/eprint/40150

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