Gandhi, Thirumanavelan and Nethaji, Munirathinam and Jagirdar, Balaji R (2003) Novel double insertion of carbon disulfide into two Ru-H bonds of [(dppm)(2)Ru(H)(2)] (dppm = Ph2PCH2PPh2): Synthesis and crystal structure of a methanedithiolate complex. In: Inorganic Chemistry, 42 (3). 667-669 .
PDF
Novel_Double_Insertion.pdf - Published Version Restricted to Registered users only Download (68kB) | Request a copy |
|
PDF
Supporting_Information.pdf - Published Supplemental Material Restricted to Registered users only Download (129kB) | Request a copy |
|
Other
ic0260320-2_s1.cif - Published Supplemental Material Restricted to Registered users only Download (22kB) | Request a copy |
Official URL: http://pubs.acs.org/doi/abs/10.1021/ic0260320
Abstract
Addition of excess carbon disulfide to cis/trans-[(dPPM)(2)Ru(H)(2)] results in the methanedithiolate complex [(dppm)(2)Ru(eta(2)-S2CH2)] 4 via the intermediacy of cis-[(dppm)(2)Ru(H)(SC(S)H)] 2. The X-ray crystal structure of this species has been determined.
Item Type: | Journal Article |
---|---|
Publication: | Inorganic Chemistry |
Publisher: | American Chemical Society |
Additional Information: | Copyright of this article belongs to American Chemical Society. |
Department/Centre: | Division of Chemical Sciences > Inorganic & Physical Chemistry |
Date Deposited: | 25 Aug 2011 09:41 |
Last Modified: | 25 Aug 2011 09:41 |
URI: | http://eprints.iisc.ac.in/id/eprint/40150 |
Actions (login required)
View Item |