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An open-framework cobalt oxalato-squarate containing a ligated amine

Dan, Meenakshi and Rao, CNR (2003) An open-framework cobalt oxalato-squarate containing a ligated amine. In: Solid State Sciences, 5 (4). 615-620 .

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Official URL: http://dx.doi.org/10.1016/S1293-2558(03)00047-5


A cobalt oxalato-squarate of the formula [Co-2(C4O4)(C2O4)(C3N2H4)(2)], containing a ligated amine has been synthesized hydrothermally and its structure determined by single crystal X-ray diffraction. The compound crystallizes in the orthorhombic space group P2(1)2(1)2 with a = 18.3845(8) Angstrom, b = 5.7884(3) Angstrom, c = 7.2598(4) Angstrom, V = 772.56(7)Angstrom(3) and Z = 4. It has a layered structure where two-dimensional sheets are formed by the connectivity of the squarate and the oxalate units with the cobalt centres, with the ligating amine molecules protruding out from the layers. (C) 2003 Editions scientifiques et medicales Elsevier SAS. All rights reserved.

Item Type: Journal Article
Publication: Solid State Sciences
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 04 Aug 2011 08:22
Last Modified: 04 Aug 2011 08:22
URI: http://eprints.iisc.ac.in/id/eprint/39756

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