Srikrishna, A and Babu, NC and Dethe, DH (2003) A convenient enantiospecific methodology for (-)-(1R,5S)-1,5-dimethylbicyclo[3.3.0]octa-2,7-dione: A formal total synthesis of (-)-ceratopicanol. In: Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry, 42 (7). pp. 1688-1690.
Full text not available from this repository. (Request a copy)Abstract
An enantiospecific formal total synthesis of (-)-ceratopicanol starting from the readily and abundantly available monoterpene (R)-limonene is described. A combination of Claisen rearrangement-intramolecular diazo-ketone cyclopropanation-regiospecific reductive cyclopropane cleavage reactions are employed for the stereo- and regiospecific generation of the two vicinal ring junction quaternary carbon atoms.
| Item Type: | Journal Article |
|---|---|
| Publication: | Indian Journal of Chemistry - Section B: Organic and Medicinal Chemistry |
| Publisher: | National Institute of Science Communication and Information Resources |
| Additional Information: | Copyright of this article belongs to National Institute of Science Communication and Information Resources. |
| Department/Centre: | Division of Chemical Sciences > Organic Chemistry |
| Date Deposited: | 03 Aug 2011 09:30 |
| Last Modified: | 03 Aug 2011 09:30 |
| URI: | http://eprints.iisc.ac.in/id/eprint/39703 |
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