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The first copper(I) complex of tris(hydroxymethyl)phosphine

Bharathi, Saravana D and Samuelson, Ashoka G and Prasad, Shashidhar J and Sridhar, MA (2001) The first copper(I) complex of tris(hydroxymethyl)phosphine. In: Inorganic Chemistry Communications, 4 (9). pp. 490-492.

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Official URL: http://dx.doi.org/10.1016/S1387-7003(01)00253-2


The first copper(I) complex of tris(hydroxymethyl)phosphine (THP) has been synthesized from a reaction with [Cu(CH3CN)4]ClO4. The crystal structure and spectroscopic properties of this complex showing the tetrahedral coordination around copper and a deprotonated THP coordinated to Cu through P are presented.

Item Type: Journal Article
Publication: Inorganic Chemistry Communications
Publisher: Elsevier Science
Additional Information: Copyright of this article belongs to Elsevier Science.
Keywords: Tris(hydroxymethyl)phosphine;Copper(I) complex;Water soluble; X-ray structure.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 02 Aug 2011 06:15
Last Modified: 02 Aug 2011 06:15
URI: http://eprints.iisc.ac.in/id/eprint/39640

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