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The hydrolytic reactivities of N-methyl-N(methylthiomethyl)acetamide and N-acetyl-1,3-thiazolidine: the influence of the sulfur atom

Chandrasekhar, Sosale and Gopalan, Srinivasa S (2002) The hydrolytic reactivities of N-methyl-N(methylthiomethyl)acetamide and N-acetyl-1,3-thiazolidine: the influence of the sulfur atom. In: Journal of Chemical Research (11). p. 532.

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Abstract

The sulfur atom in the substrates leads to modest enhancements in the titled phenomena: these are essentially derived from favourable enthalpies of activation, the negative entropies of activation possibly indicating a measure of stereoelectronic control.

Item Type: Journal Article
Publication: Journal of Chemical Research
Publisher: Science Reviews 2000 Ltd
Additional Information: Copyright of this article belongs to Science Reviews 2000 Ltd.
Keywords: sulfur atom;N-methyl-N-(methylthiomethyl)acetamide;N-acetyl-1,3-thiazolidine
Department/Centre: Division of Chemical Sciences > Organic Chemistry
Date Deposited: 27 Jul 2011 06:01
Last Modified: 27 Jul 2011 06:01
URI: http://eprints.iisc.ac.in/id/eprint/39472

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