Kumaran, Senthil S and Ramesh, KP and Ramakrishna, J (2002) Proton NMR T-1 studies in methylammonium trichloro stannate(II) (CH3NH3SnCl3). In: Phase Transitions: A Multinational Journal, 75 (6). 597-605 .
Full text not available from this repository. (Request a copy)Abstract
Proton spin lattice relaxation time (T-1) measurements have been carried out in methylammonium trichloro stannate(II) (CH3NH3SnCl3) as a function of temperature in the range 317-5 K at a Larmor frequency of 10 MHz. The temperature dependence of T-1 shows a phase transition around 220 K and four T-1 minima (294 K, 62 K, 32 K and 12 K). The results are discussed in terms of proton dynamics, namely, uncorrelated reorientation of NH3 and CH3 groups at high temperatures and tunnelling of NH3 and CH3 protons at low temperatures.
Item Type: | Journal Article |
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Publication: | Phase Transitions: A Multinational Journal |
Publisher: | Taylor and Francis Group |
Additional Information: | Copyright of this article belongs to Taylor and Francis Group. |
Keywords: | Phase transition;Proton tunnelling;Uncorrelated reorientation;Nuclear spin lattice relaxation time |
Department/Centre: | Division of Physical & Mathematical Sciences > Physics |
Date Deposited: | 03 Aug 2011 13:08 |
Last Modified: | 03 Aug 2011 13:08 |
URI: | http://eprints.iisc.ac.in/id/eprint/39370 |
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