Orthometalation in calixarenes: Synthesis and structural characterization of a novel orthopalladated calix[4]arene bisphosphite

Mahalakshmi, L and Krishnamurthy, SS and Nethaji, M (2002) Orthometalation in calixarenes: Synthesis and structural characterization of a novel orthopalladated calix[4]arene bisphosphite. In: Current Science (Bangalore), 83 (7). pp. 870-873.

Preview

PDF Orthometalation_in_calixarenes.pdf - Published Version Download (236kB)

Abstract

The treatment of a symmetrically bridged p-Bu-t-calix[4] arene bisphosphite with PdCl2(NCPh)(2) yields a novel orthopalladated derivative by a C-C bond scission of a t-butyl group attached to an aryl ring. The structure of this orthopalladated calix[4]arene derivative has been established by X-ray crystallography.

Item Type:	Journal Article
Publication:	Current Science (Bangalore)
Publisher:	Indian Academy of Sciences
Additional Information:	Copyright of this article belongs to Indian Academy of Sciences.
Department/Centre:	Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited:	21 Jul 2011 09:09
Last Modified:	21 Jul 2011 09:09
URI:	http://eprints.iisc.ac.in/id/eprint/39330

Actions (login required)

View Item