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Mechanistic Studies on Self Deflagrating Solids from temperature profile analysis

Kishore, K and Patil, KC and Gajapathi, D (1985) Mechanistic Studies on Self Deflagrating Solids from temperature profile analysis. In: Propellants, Explosives, Pyrotechnics, 10 (6). pp. 187-191.

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A preliminary investigation has been made to study the mechanism of decomposition of self deflagrating solid (iron oxalate dihydrazinate) using temperature profile technique. A three step decomposition mechanism of two hydrazine losses and subsequent oxidation of anhydrous salt has been proposed. The enthalpy changes for these steps, obtained from the temperature profile measurements agree well with the values calculated using heat of formation data obtained from combustion calorimetry and differential scanning calorimetry.

Item Type: Journal Article
Publication: Propellants, Explosives, Pyrotechnics
Publisher: Verlag GmbH & Co. KGaA, Weinheim
Additional Information: The copyright belongs to Verlag GmbH & Co. KGaA, Weinheim.
Department/Centre: Division of Chemical Sciences > Inorganic & Physical Chemistry
Date Deposited: 28 Oct 2005
Last Modified: 27 Aug 2008 11:31
URI: http://eprints.iisc.ac.in/id/eprint/3914

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