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A new layered iron fluorophosphate

Choudhury, Amitava (2002) A new layered iron fluorophosphate. In: Proceedings of the Indian Academy of Sciences - Chemical Sciences, 114 (2). pp. 93-105.

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A new iron fluorophosphate of the composition, [C6N4H21] [Fe2F2(HPO4)(3)][H2PO4](.)2H(2)O, I has been prepared by the hydrothermal route. This compound contains iron fluorophosphate layers and the H2PO4- anions are present in the interlayer space along with the protonated amine and water molecules. The compound crystallizes in the monoclinic space group P2(1)/c. (a = 13-4422(10) Angstrom, b = 9 7320(10) Angstrom, c = 18-3123(3) Angstrom, beta = 92-1480degrees, V = 2393-92(5) Angstrom 3, Z = 4, M = 719-92, d(calc). = 1.997 g cm(-3), R-1 = 0.03 and wR(2) = 0,09).

Item Type: Journal Article
Publication: Proceedings of the Indian Academy of Sciences - Chemical Sciences
Publisher: Indian Academy of Sciences
Additional Information: Copyright of this article belongs to Indian Academy of Sciences.
Keywords: Open-framework materials;layered iron phosphate;hydrothermal synthesis.
Department/Centre: Division of Chemical Sciences > Solid State & Structural Chemistry Unit
Date Deposited: 04 Aug 2011 05:48
Last Modified: 04 Aug 2011 05:48
URI: http://eprints.iisc.ac.in/id/eprint/38981

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